Does entropy change in a polytropic process?

The polytropic process is defined as such that pVm=A, where A is a constant. Generally, the change in entropy is ΔS=nRlnVV0+nCVlnTT0. which is the formula for ΔS in polytropic process and γ=Cp/CV. According to Wikipedia, for m<0 II law of thermodynamics would be violated.

What is polytropic compression?

A polytropic process is a thermodynamic process that obeys the relation: where p is the pressure, V is volume, n is the polytropic index, and C is a constant. The polytropic process equation can describe multiple expansion and compression processes which include heat transfer.

What is the value of n for the compression?

The value of n can vary from zero to infinity. n=0 for an isobaric process, in which the pressure of the system stays constant: ΔP = 0. n= infinity for an isochoric process, when volume stays constant i.e., ΔV = 0.

Is there heat transfer in polytropic process?

The term “polytropic” was originally coined to describe any reversible process on any open or closed system of gas or vapor which involves both heat and work transfer, such that a specified combination of properties were maintained constant throughout the process.

Which of the following is true for a polytropic process?

Which of the following is true for a polytropic process? Explanation: These are the properties of an adiabatic process. Explanation: It comes from the p1*(v1^n) = p2*(v2^n).

What is the difference between adiabatic and polytropic process?

The key difference between adiabatic and polytropic processes is that in adiabatic processes no heat transfer occurs whereas in polytropic processes heat transfer occurs. In chemistry, we divide the universe into two parts.

Is compression a polytropic process?

Real compression processes operate between adiabatic and isothermal compression. Actual compression processes are polytropic processes. This is because the gas being compressed is not at constant entropy as in the adiabatic process, or at constant temperature as in the isothermal processes.

Is polytropic the same as isentropic?

Isentropic process is one in which the entropy remains constant throughout. Polytropic process is one which obeys the law given below throughout the process.

Is compression positive or negative work?

Work of compressions is negative for the surroundings, but work of compression is positive for the system, because the system isn’t applying any force. Instead, the surroundings are creating the pressure through compressions, making work negative.

Does polytropic mean constant temperature?

the case n = 1, pV = constant, corresponds to an isothermal (constant-temperature) process. the case n = , pV = constant, corresponds to an isentropic (constant-entropy) process.

How do you find the internal energy of a polytropic process?

If you know the initial and final values of temperature, then you know the change in internal energy. ΔU=nCvΔT, where n is determined from the ideal gas law.

How do you calculate the polytropic coefficient of compression?

Word of caution: Many gas compression and expansion processes may be approximated by a polytropic process. In each case, the polytropic coefficient must be determined experimentally by measurement of the heat and work transfer and the initial and final states. In isentropic expansion and compression n = Y [Gamma] = Cp/Cv

What is the polytropic index of a thermodynamic process?

In reality, however, a thermodynamic process can be neither infinitely slow nor infinitely fast, so that the actual process will run between these two limiting cases. Consequently, the polytropic index will have a value between 1 (isothermal process) and κ (isentropic process).

What is the relation between polytropic coefficient and ratio of energy transfers?

Equivalence between the polytropic coefficient and the ratio of energy transfers. For an ideal gas in a closed system undergoing a slow process with negligible changes in kinetic and potential energy the process is polytropic, such that where C is a constant, , , and with the polytropic coefficient .

What is the relationship between entropy and Cp/Cv?

Cp/Cv is a measure of how much internal energy is getting converted to work in any compression/expansion process. Every change in internal energy impacts entropy changes and brings irreversibility in the process.